![]() One Latin connotation for the word “mole” is “large mass” or “bulk,” which is consistent with its use as the name for this unit. It provides a specific measure of the number of atoms or molecules in a sample of matter. The mole is an amount unit similar to familiar units like pair, dozen, gross, etc. ![]() This experimental approach required the introduction of a new unit for amount of substances, the mole, which remains indispensable in modern chemical science. Today, sophisticated instruments allow the direct measurement of these defining microscopic traits however, the same traits were originally derived from the measurement of macroscopic properties (the masses and volumes of bulk quantities of matter) using relatively simple tools (balances and volumetric glassware). However, because a hydrogen peroxide molecule contains two oxygen atoms, as opposed to the water molecule, which has only one, the two substances exhibit very different properties. For example, water, H 2O, and hydrogen peroxide, H 2O 2, are alike in that their respective molecules are composed of hydrogen and oxygen atoms. The identity of a substance is defined not only by the types of atoms or ions it contains, but by the quantity of each type of atom or ion. The few exceptions to this guideline are very light ions derived from elements with precisely known atomic masses. Even when calculating the mass of an isolated ion, the missing or additional electrons can generally be ignored, since their contribution to the overall mass is negligible, reflected only in the nonsignificant digits that will be lost when the computed mass is properly rounded. Moreover, the mass of an electron is negligibly small with respect to the mass of a typical atom. Even though a sodium cation has a slightly smaller mass than a sodium atom (since it is missing an electron), this difference will be offset by the fact that a chloride anion is slightly more massive than a chloride atom (due to the extra electron). This approach is perfectly acceptable when computing the formula mass of an ionic compound. Note that the average masses of neutral sodium and chlorine atoms were used in this computation, rather than the masses for sodium cations and chlorine anions. Figure 3.2 outlines the calculations used to derive the molecular mass of chloroform, which is 119.37 amu.įigure 3.4 Table salt, NaCl, contains an array of sodium and chloride ions combined in a 1:1 ratio. The average molecular mass of a chloroform molecule is therefore equal to the sum of the average atomic masses of these atoms. The molecular formula of chloroform indicates that a single molecule contains one carbon atom, one hydrogen atom, and three chlorine atoms. Consider chloroform (CHCl 3), a covalent compound once used as a surgical anesthetic and now primarily used in the production of tetrafluoroethylene, the building block for the "anti-stick" polymer, Teflon. Formula Mass for Covalent Substancesįor covalent substances, the formula represents the numbers and types of atoms composing a single molecule of the substance therefore, the formula mass may be correctly referred to as a molecular mass. These ideas can be extended to calculate the formula mass of a substance by summing the average atomic masses of all the atoms represented in the substance’s formula. Formula MassĪn earlier chapter of this text described the development of the atomic mass unit, the concept of average atomic masses, and the use of chemical formulas to represent the elemental makeup of substances. Understanding the relationship between the masses of atoms and the chemical formulas of compounds allows us to quantitatively describe the composition of substances. ![]() ![]() For example, Dalton’s atomic theory was an attempt to explain the results of measurements that allowed him to calculate the relative masses of elements combined in various compounds. Many argue that modern chemical science began when scientists started exploring the quantitative as well as the qualitative aspects of chemistry.
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Also, plenty of nice touches in the gauntlet design, too, despite no visible infinity stones. ThanosĪnother perfect marriage of form and function here as the scythe weapon provides a fitting win animation for the destroyer of worlds. Attention to detail in the face modelling here shows this was a labor of love, which we greatly appreciate. No wait, now we see, he's the biggest man in the world and made of solid gold! Fourteen carat gold! We'd better take a hike now that he's running things, all hail King Homer! Robbie RottenĪ very fitting tribute for the dearly departed Stefan Karl Stefansson, Lazytown actor who died in August leaving many fans of the show's villain Robbie Rotten devastated. Also posing like Ivy in front of the backdrop from Botticelli's Birth of Venus painting is just too much, on top of all the other stuff that makes this too much. Tingle, the man too old to keep trying to become a fairy, is now wearing skin-tight shiny Lycra and a red codpiece. Speaking of surprisingly jacked mascots, oh no. ![]() ![]() Why is Pikachu so buff? What happened that made him want to get this jacked? God I hope he doesn't hurt anyone with Cervantes' move set, that's one dangerous combination. Now this is a more battle-appropriate Pokemon. It's like one of those transformers costumes where the kids fold down into cars. Of all the Pokemon you'd want to take into a battle, why Magikarp? Why? The most impressive thing about this Soulcalibur VI custom character is the way it only becomes the Magikarp once Voldo enters his crab formation and begins Splashing. Also of note, the perfect placement of a single bright blue eyeball. It's quite an achievement to make the skeleton model in Soulcalibur VI look fat, but it does appear possible with the help of this fetching blue coat. Never has a spooky stand-up skeleton looked more menacing. What happens if Geralt wears the Super Crown? We must know. We're interested in what this totally canon appearance means for the deep Super Crown lore that has been evolving over the past few weeks. When fandoms collide! As well as alongside Boosette in this article's header, Bowsette appears here in her alternate (read: correct) redhead representation. Now if only there were three other nuts and a way of putting different colored bandanas on each. Based appropriately on Raphael, this mutant ninja nut was the first bizarre creation we saw leaking out of the Soulcalibur VI custom characters community and remains one of our favorites. ![]() ![]() The man(?) that started it all, a true hero in a full-shell. If you have any better masterpieces, make sure we see them! Best Soulcalibur VI custom characters gallery Pistachio What follows is a few of our favorites, with familiar faces and bizarre approximations of well-loved characters from popular culture. The Soulcalibur VI custom characters are hilarious and awe-inspiring, as people push the limits of Create-A-Soul to the edges of human creativity. Snappy inputs, throw breaks and match-turning Reversal Edges make for nail-biting gameplay, but the community is really outdoing itself in one particular arena: Character creation. Soulcalibur VI has been blowing up the fighting game community over the past week with some of the best combat in the series' history. ![]() People exploring a sexual relationship after many years of not being sexually active Women experiencing the genital symptoms of menopause for whom vaginal penetration may be painful People whose sex has been negatively impacted by health status or aging This Yes/No/Maybe Checklist is a fillable pdf and is also found on the Resources tab of the Home page. It is not as extensive as Bex Caputo’s or Scarleteen’s list, but it does offer a look at what a colourful and engaging Y/N/M list could look like.A Yes/No/Maybe Checklist can help kindle a conversation about sex with a partner, as well as expand sexual repertoire. I found this list to be very engaging because of its design. The cool feature of Autostraddle’s Y/N/M list is that it is actually a set of worksheets that are quite visually appealing. The lists consider positions in giving and receiving and ask how frequently one wants to feel a particular emotion: often, sometimes, or never. ![]() Caputo explores a few options: Yes – Into, Yes – Willing, Maybe, No. It asks what kind of activities one wants to explore what one want to be called in bed what kind of emotions one want to feel while engaging in sex and kink. It’s quite exhaustive because it covers sex, kink, language, and feelings. There is one for those who are “vanilla” and want to explore their sexuality.īex Caputo’s Superpowered Yes/No/Maybe List.īex Caputo’s Y/N/M list is a bit different from the other ones on this list. Sexuality educator and pleasure advocate Sunny Megatron shares two Y/N/M lists in the link above. Often, these little details are overlooked when people engage in intimacy, so it’s great that Scarleteen’s checklist dives into some of these finer details. Scarleteen’s sexual inventory checklist is very thorough and covers a lot of ground as it discusses body boundaries such as boundaries about direct eye contact. ![]() ![]() Scarleteen’s Yes/No/Maybe So: A Sexual Inventory Checklist. They are great places to start conversations and, when you get more experience with them, you can create your own! Here are some Yes/No/Maybe checklists you can take a look at. Respect, consent and ongoing communication with each other are key points here.
![]() ![]() In addition to the Afterglow headset itself, the package includes essential accessories to complement your setup. ![]() The attention to comfort and ergonomics is unmistakable, setting the stage for a truly enjoyable and immersive audio experience. The soft cushioning and adjustable headband further emphasize the thoughtful design, ensuring that the headset can be tailored to your specific preferences for extended periods of use. The attention to detail is evident, from the premium materials used in its construction to the meticulous placement within the packaging, ensuring that every aspect of the unboxing experience reflects the exceptional quality of the Afterglow headset.Īs you carefully lift the Afterglow headset from its secure position, you'll notice its lightweight yet durable construction, designed to provide both comfort and longevity. The smooth contours and striking accents of the headset immediately convey a sense of sophistication and cutting-edge technology. Upon lifting the lid, you'll find the Afterglow headset nestled snugly within the packaging, showcasing its modern and eye-catching design. The Afterglow headset is thoughtfully presented, exuding a sense of anticipation and excitement as you prepare to delve into a world of immersive audio experiences. The packaging is carefully crafted to ensure that your new audio companion arrives in pristine condition, reflecting the premium quality of the product within. As you eagerly unbox your Afterglow headset, you're greeted with a sleek and stylish design that immediately captures your attention. ![]() Then, use project management software to program recurring events into your daily schedule. These events may include weekly team meetings, a monthly book club, or phone calls with clients. Once you’ve noted the deadlines in your online to-do list, highlight any events that happen on a recurring basis. Read: Write better SMART goals with these tips and examples 4. By creating these deadlines, you can ensure that you’ll be in shape by the time the race arrives. For example, if you plan to run a half marathon, you should set training deadlines for how many miles to run per week. You can create your own deadlines for personal tasks to hold yourself accountable. Tip: Deadlines don’t only apply to work projects. In fact, unclear processes are the second-largest contributing factor in missed deadlines Without clear deadlines, you might accidentally miss a deliverable-even though you had plenty of time to work on it. Like priorities, deadlines tell you which tasks are most important and when you need to get your work done. If you aren’t sure what the deadline should be, select a deadline that makes sense for now-after all, you can always update it later. If you haven’t already, go through your online to-do list and make sure every task has a deadline. See if there’s any work you can delegate or defer. When deadlines conflict, ask for help from your team members and your manager. For example, if one project is for a client and the other is for your boss, then the client project will likely come first. Tip: If you have tasks that conflict with one another, consider which task is most urgent. Which tasks will I stress about if I don't complete them soon? Which tasks must I complete on specific days? Some questions you can ask yourself when sorting through your tasks include: To prioritize your work, begin by marking each task as high, medium, or low priority. That way, if it seems like you won’t be able to finish all of your tasks on a given day, you can focus on the ones that are the highest priority-in other words, the ones that will have the highest impact. When you prioritize work, you gain a clearer sense of what needs to get done when. Your list will feel more organized once you prioritize. Prioritize tasksĭon’t fret if you feel overwhelmed after creating your to-do list. ![]() You can always add more to-do items to your list as they arise. Tip: It’s ok if you don’t know every task that’s coming up in the week ahead. For example, if you want to include “go to lunch” as a recurring task to add daily structure, go ahead. You can decide how specific to get with your task list. Also include one-off tasks like deadlines or phone calls. Include recurring tasks in your list like meetings, exercise, and appointments. You can add these items one by one to your scheduling app so you know you’ve recorded them, or use a technique like the Getting Things Done (GTD) method to systematically capture everything you need to get done. Then, you can simply copy the template, update it with today's tasks, and get to work.īefore you can organize your to-dos, you first need to make a list of all the items you need to do for the day. You can use the same outline for your schedule every day-a daily schedule template. That's where a daily schedule comes in-you can book time in your daily calendar for everything you need to accomplish in the next 24 hours. ![]() Juggling this mental to-do list is exhausting, and more often than not, it doesn't help you get the work done. Free daily schedule template What is a daily schedule template?Įvery day, you go through a routine set of tasks, both at work and in your personal life. With daily planning, you can set yourself up for success, even on days when you don’t feel all that productive. Today, you'll learn the importance of a daily schedule for time management. When you have a clear understanding of how you're using your time, you won’t always feel like you’ve run out of it. ![]() By separating out each block, you can dedicate specific time for working, socializing, eating, and creating. When this happens, it can be helpful to think of a day not as a single unit but as 24 hour-long blocks of time. Sometimes it feels like you don't have enough hours in the day. Plus, by visualizing your work in multiple ways, you can plan your day and set yourself up for success. When you create your daily schedule template in an online tool, you’ll have the added flexibility to make changes and track updates in real-time. It can give you structure, reduce stress, and increase productivity. A daily schedule is an excellent way to manage life’s moving parts. ![]() It’s an amazing way to learn about history while having fun playing a game. With this mod, you can immerse yourself in the Thirty Year’s War, explore the peak of the pike and shot era between 15, and discover what it was like to live during this time period. It brings the age of shot and pike to life with its realistic and historical changes to every aspect of the game. The Pike and Shot: Total War mod for Napoleon: Total War is a great way to get an interactive look at the 17th-century political situation in Europe. Nautical Nate’s Diversity Mod adds a wide range of uniforms to the game, from both primary and secondary factions to different unforms based on role, in order to accurately portray the variety of uniforms used during the first World War. It makes sense that a game as serious as Napoleon: Total War should reflect this important piece of history. They have also served as a way for soldiers to show their allegiance to their country and its values. Throughout the centuries, military uniforms have evolved to reflect changing times and technologies. Military uniforms have a long and storied history, dating back to the earliest days of organized warfare. Here we present some of our top picks from among the best Napoleon: Total War mods available today! 15. Nautical Nate’s Great War Diversity Modįrom improved visuals to new campaigns and scenarios, these mods offer something for everyone. READ MORE: Third Age Total War mod how to install it. The other mods also have their own installation methods, but if you just read along you'll be able to follow the instructions with ease. You may then have to activate them in-game, but they should all explain how these things work. All you need to do is go to the Workshop section (or use the links above) and then hit Subscribe on the mods you want. With the ones on Steam, it's incredibly easy to install them. Realism+: A mod that alters a huge number of things subtlyĪll of these mods should mostly work together, but make sure you always keep save states handy just in case.ĮAD MORE: Everything you can craft in Baldur’s Gate 3 How to install Total War: Shogun 2 mods.Additional Units Mod: This one gives you extra units to use.S hogun 2 Overhaul Project: A graphical boost to the old game.One Turn Research: Speeds the game up a bit.Darth Mod: Tweaks the AI to be a little better.There is a staggeringly large number of mods out there for this game, and despite it being rather old, it still gets new ones here and there. However, if you're hoping to change things up a bit for this classic game, then you'll need the best Total War: Shoguns 2 mods, and that's what we have here. It features all of the classic hallmarks of the series that you'd expect, and that means you're in for an incredible strategy game. While the game is nine-years-old, it's still an excellent strategy game, and it's probably going to be your strategy game of choice if you like the setting. If you've been enjoying the Total War series but have yet to check out Total War: Shogun 2, then you're really missing out. He is a former naval officer, Goldman Sachs investment banker and film producer. Unkempt and unpolished, Bannon is the opposite of a career politician. Steve Bannon knows what he’s doing and he will act as a gravitational pull on the rest of the right because they have to match him.” “Donald Trump does not look at Steve Bannon and think this guy is unhinged he’s looking at Steve Bannon and saying this is exactly what I want to hear from my supporters. “Steve Bannon is still peddling the most powerful meth out there. Sykes makes an analogy with drug dealers competing with each other by selling purer and stronger forms of methamphetamine, a highly addictive stimulant. The Maga-regalia wearing crowd went wild, cementing Bannon’s status as a tribune of the movement heading into the 2024 presidential election.Ĭharlie Sykes, a political commentator and author of How the Right Lost Its Mind, said: “At the moment Steve Bannon is the id of the American right and, if we’ve learned anything in the last eight years, it’s don’t assume because somebody sounds extreme and unhinged that they will not be influential in this party.” “Biden, you and your crime family are nothing but trash, OK? And on 20 January of 2025 we’re going to take out the trash.” On the main stage, Bannon compared Trump to the Roman general Cincinnatus and declared: “His fate and destiny is to have the greatest political comeback in American history from November 5 to drive the vermin out of 1600 Pennsylvania Avenue. In the meantime, he hosts a regular podcast called War Room, which propagates false narratives about the 2020 election and coronavirus vaccines but is given a veneer of respectability by guests including Elise Stefanik, the No 3 Republican in the House of Representatives, and other senior politicians.Ī pop-up War Room studio commanded a prime location at CPAC last week and featured guests such as Liz Truss, the former British prime minister. The committee heard evidence that Trump spoke to Bannon at least twice on January 5 and predicted that “all hell is going to break loose tomorrow”. I can work with him on figuring that out but I can’t keep a wedding timeline with that.The former White House chief strategist may not be in daily contact with Trump any more but it scarcely matters: he is a vital source for the far-right ecosystem that shapes and animates the “Make America great again” (Maga) base.īannon, 70, is currently appealing a criminal conviction and four-month prison sentence for defying a subpoena from the congressional committee investigating the Januattack on the US Capitol. ![]() We are pretty early into wedding planning and I want to call it off because weddings are expensive and I’m not sinking more of my money into an uncertainty.įiguring out whether he wants to get married will take time and time is money. That’s where his lack of enthusiasm comes from. The joke made me realize that he probably doesn’t want to get married. I let it go after I felt like I was nagging him to have an opinion on something He said he doesn’t care about the details at all. I don’t even need him to have initiative but an opinion would be nice. AITAH?Įdit: I’ve talked with him about his lack of enthusiasm about anything. He said it was normal to joke about this. He was very upset that I called off the wedding and said he was just joking. ![]() We haven’t sent out RSVPs or booked too many vendors yet so I want to call it off before it becomes an even more expensive mistake. I talked to my fiancé and said that I’m going to call off the wedding plans and we could re-evaluate if he really wants to get married or even stay in this relationship. ![]() He wasn’t interested in getting married and I don’t want to marry someone who doesn’t enthusiastically want to get married. I decided we should call off the wedding for now. I felt really upset that he didn’t acknowledge my hard work in planning the wedding and because he joked that I was trapping him into marriage and that I pushed him into getting married. He said he was trying to enjoy his last days of freedom before I trapped him in the marriage. ![]() My fiancé joked that he didn’t lock me down, I locked him up. I was telling them some of my plans to cut costs down and my friend made a joke that it was a good thing my fiance locked me down because I’m a professional. My fiancé and our friends were talking about the wedding. His default response is “whatever you want.” So, I’ve had full creative freedom but I am a little sad he didn’t contribute to anything, even the color scheme. My fiance has ADHD and finds planning very boring. I work in the events industry and this sort of thing is my passion. It was a beautiful intimate proposal and I loved the idea of telling our future kids about his proposal. ![]() ![]() Some monitoring and alerts may not be available to you if the information you enter at enrollment does not match the information in your credit file at (or you do not have a file at) one or more consumer reporting agencies.ĬreditWise Alerts are based on changes to your TransUnion and Experian® credit reports and information we find on the dark web. ![]() The availability of the CreditWise tool depends on our ability to obtain your credit history from TransUnion. After you log in, you can navigate to the Help Center, where you can find quick actions to manage your freeze and toggle your freeze status to 'Unfrozen. Your CreditWise score can be a good measure of your overall credit health, but it is not likely to be the same score used by creditors. To unfreeze your Experian credit report, log in to your Experian account or create one for free. Your CreditWise score is calculated using the TransUnion® VantageScore® 3.0 model, which is one of many credit scoring models. The third parties listed are solely responsible for their products and services, and all trademarks listed are the property of their respective owners. The EMVCo Contactless Symbol and Contactless Indicator, consisting of four graduating arcs, are trademarks owned by and used with permission of EMVCo, LLC.Ĭapital One does not provide, endorse or guarantee any third-party product, service, information, or recommendation listed above. For specific advice about your unique circumstances, consider talking with a qualified professional. Our content is not intended to provide legal, investment or financial advice or to indicate that a particular Capital One product or service is available or right for you. ![]() Since this person is coming in with a “clean slate” mindset, are there fresh insights you’d like them to contribute?.Who are the key stakeholders this person needs to know about?.What quick wins can they ship to gain momentum?. ![]()
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